Bubble stream motion in a magnetic subject. a, b Sketch of the magneto-electrochemical system and think about of the electrochemical cell. c Variation of the angle of motion of the H2 bubble stream with respect to the vertical (φ) as a operate of the response present and the path of the magnetic subject. A detrimental magnetic subject worth refers back to the identical magnetic subject power however with the reverse path. d Deviation angle (φ) for H2 bubbles (HER) and for O2 bubbles (OER), as a operate of the magnetic subject power when absolutely the response present was 1 mA. Credit score: Nature Communications (2024). DOI: 10.1038/s41467-024-46980-8
In an period the place the hunt for sustainable vitality sources has turn out to be paramount, researchers are tirelessly exploring revolutionary avenues to reinforce gas manufacturing processes. One of the essential instruments in changing chemical vitality into electrical vitality and vice versa is electrocatalysis, which is already utilized in varied green-energy applied sciences.
Electrocatalysis hurries up electrochemical reactions by means of the usage of catalysts—substances that enhance response charges with out being consumed themselves. Electrocatalysis is key in gadgets like fuel cells and electrolyzers, the place it allows the environment friendly transformation of fuels similar to hydrogen and oxygen into electrical energy, or water into hydrogen and oxygen, respectively, facilitating a cycle of unpolluted vitality.
However the issue is effectivity. Conventional electrocatalysis strategies usually fall in need of maximizing the transport of reactants to the catalyst’s floor, which is a key step in vitality conversion. This lowers the response’s total effectivity, and slows down our progress in the direction of clear vitality options.
Now, scientists led by Magalí Lingenfelder at EPFL have developed a novel strategy to trace the basic processes that improve the effectivity of unpolluted gas manufacturing. Revealed in Nature Communicationsthe work centered on the promising intersection of magnetic fields and electrocatalysis, providing a pathway to extra environment friendly and environmentally pleasant gas manufacturing applied sciences.
The research confirmed that surrounding the catalysts with magnetic fields creates Lorentz forces—the forces that magnetic fields exert on transferring electrical prices. These in flip induce whirling motions that improve the motion of reactants and merchandise on the catalyst floor, guaranteeing a extra constant and speedy response but in addition overcoming the restrictions posed by reactant shortage, a standard hurdle in reactions just like the oxygen discount response (ORR), important for gas cells.

Response kinetics and mass transport results in electrocatalysis. Credit score: Nature Communications (2024). DOI: 10.1038/s41467-024-46980-8
To do all this, the researchers needed to construct a instrument for observing the motion of ions in actual time below a magnetic subject, utilizing a complicated magneto-electrochemical setup. For the precise subtle setup, Lingenfelder turned to her workplace neighbor and spintronics professional, Professor Jean-Philippe Ansermet, who had additionally studied spin results in electrochemistry.
“We adapted Jean-Philippe’s electromagnet to measure magnetic field effects on key electrocatalytic reactions for green energy,” she says. “Using a creative trick developed by Priscila and Yunchang (the first authors of the study), we were able to track in situ how ions move in the electrolyte under a magnetic field and to provide a solid ground on how to apply magnetic fields to boost electrocatalysis in a reproducible way.”
By making use of magnetic fields to non-magnetic electrodes and monitoring reactions, the scientists have been capable of decouple the completely different results and observe how magnetic forces can stir and improve the motion of reactants across the catalyst. This course of, akin to creating miniature whirlpools, considerably improves the effectivity of reactions essential for inexperienced hydrogen manufacturing, providing a promising avenue for advancing sustainable vitality applied sciences.
Is the brand new technique sensible? Within the research, the scientists present greater than a 50% increase in exercise for the oxygen discount response induced by magnetic fields on non-magnetic interfaces. This represents a considerable bounce in effectivity, however, most significantly, allowed the staff to resolve many elementary controversies within the subject by demonstrating the mechanisms and situations wanted for magnetic fields to reinforce completely different electrocatalytic reactions involving gasoline merchandise or reactants like hydrogen and oxygen.
The research charts the best way in the direction of utilizing magnetic fields to enhance the effectivity of electrocatalysis that may propel us in the direction of more practical sustainable gas manufacturing. It may revolutionize vitality conversion applied sciences, make gas cells extra broadly adopted e.g., in hydrogen automobiles, and enhance the manufacturing of hydrogen as a clear vitality supply, additionally mitigating the affect of our vitality consumption on the planet’s local weather change.
Extra info:
Priscila Vensaus et al, Enhancement of electrocatalysis by means of magnetic subject results on mass transport, Nature Communications (2024). DOI: 10.1038/s41467-024-46980-8
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