Tuesday, April 29, 2025

Storing and utilizing energy with innovative sulfur-based cathodes

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Conceptual diagram of the in-situ Raman spectra check system. Credit score: Utilized Chemistry Worldwide Version (2024). DOI: 10.1002/anie.202400382

Electrical autos and transportable digital gadgets reminiscent of laptops and cellphones are unthinkable with out lithium-ion batteries. The issue is extremely poisonous supplies reminiscent of cobalt are sometimes used for the cathodes of those batteries, which jeopardize the atmosphere and the well being of individuals within the international locations the place they’re mined. As well as, the reserves of those metals are very restricted.

A analysis workforce at Humboldt-Universität zu Berlin (HU) has now achieved a decisive breakthrough in battery know-how. The workforce, led by Prof Dr. Michael J. Bojdys, has developed a high-performance sulfur-based cathode.

Sulfur is a sustainable various to the supplies generally utilized in lithium-ion batteries as a result of it’s much less poisonous and—not like cobalt—is ample. Nonetheless, the storage capability of batteries wherein sulfur is used as a cathode materials has to this point declined quickly.

The researchers have now been in a position to clear up this downside. The results of the study have been printed in utilized Chemistry.

“Our development paves the way for sulfur electrodes as a viable alternative to conventional metal-based cathodes. It could fundamentally change the way we store and use energy and represents an important step towards a more sustainable future,” explains Prof Bojdys.

Fixing the sulfur-shuttle downside utilizing polymer chemistry

With sulfur-based cathodes, the mobility of the sulfur has to this point led to a degradation of the battery—an impact referred to as the sulfur-shuttle. Within the newly developed resolution, the sulfur is encapsulated in a particular microporous polymer community in order that the sulfur particles are retained. This battery know-how not solely will increase the efficiency and repair lifetime of batteries but additionally avoids the issue of scarce sources.

Prof Dr. Michael J. Bojdys is an skilled in sustainable power supplies and helps to remodel the chemical business within the Berlin capital area by combining science and business to create a circular economy based mostly on sustainable uncooked supplies.

Extra data:
Guiping Li et al, One‐pot Synthesis of Excessive‐capability Sulfur Cathodes by way of In‐situ Polymerization of a Porous Imine‐based mostly Polymer, Utilized Chemistry Worldwide Version (2024). DOI: 10.1002/anie.202400382

Supplied by Humboldt College of Berlin

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Storing and using power with revolutionary sulfur-based cathodes (2024, April 24)
retrieved 24 April 2024
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