Tuesday, April 29, 2025

Discovery brings all-solid-state sodium batteries closer to practical use

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Graphical summary. Credit score: Power Storage Supplies (2024). DOI: 10.1016/j.ensm.2024.103307

The pursuit of greener vitality additionally requires environment friendly rechargeable batteries to retailer that vitality. Whereas lithium-ion batteries are at the moment essentially the most broadly used, all-solid-state sodium batteries are attracting consideration as sodium is way extra plentiful than lithium. This could make sodium batteries cheaper, and solid-state batteries are considered safer, however processing points imply mass manufacturing has been troublesome.

Osaka Metropolitan College Affiliate Professor Atsushi Sakuda and Professor Akitoshi Hayashi, each of the Graduate College of Engineering, led a analysis workforce in growing a course of that may result in mass synthesis for sodium-containing sulfides. The outcomes had been printed in Energy Storage Materials and Inorganic Chemistry.

Utilizing sodium polysulfides (sulfides with two or extra atoms of sulfur) as each the fabric and the flux, which promotes fusion, the workforce created a strong sulfide electrolyte with the world’s highest reported sodium ion conductivity—about 10 instances greater than required for sensible use—and a glass electrolyte with excessive discount resistance.

Mass synthesis of such electrolytes with excessive conductivity and formability is essential to the sensible use of all-solid-state sodium batteries.

“This newly developed process is useful for the production of almost all sodium-containing sulfide materials, including solid electrolytes and electrode active materials,” Professor Sakuda stated.

“Also, compared to conventional methods, this process makes it easier to obtain materials that display higher performance, so we believe it will become a mainstream process for the future development of materials for all-solid-state sodium batteries.”

Extra info:
Akira Nasu et al, Using reactive polysulfides flux Na2S for the synthesis of sulfide strong electrolytes for all-solid-state sodium batteries, Power Storage Supplies (2024). DOI: 10.1016/j.ensm.2024.103307

Tomoya Otono et al, Excessive-Sodium-Focus Sodium Oxythioborosilicate Glass Synthesized by way of Ambient Stress Methodology with Sodium Polysulfides, Inorganic Chemistry (2024). DOI: 10.1021/acs.inorgchem.3c04101

Quotation:
Discovery brings all-solid-state sodium batteries nearer to sensible use (2024, April 11)
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