Monday, April 28, 2025

Hybrid anode material advances lithium-ion battery technology

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A novel composite materials, combining the conductivity of graphene oxide with the power storage capability of nickel-iron compounds, is proven. This fastidiously engineered construction, that includes managed interfaces and nanoscale structure, provides a promising pathway to develop high-performance lithium-ion batteries for future functions. Credit score: Jae-Min Oh, Dongguk College

Lithium-ion batteries are the dominant power storage expertise powering all the things from moveable electronics to electrical autos and renewable power programs. Nonetheless, the demand for larger power density, sooner charging, and longer lifespans necessitates steady innovation.

Researchers, led by Professor Jae-Min Oh of Dongguk College, in collaboration with Seung-Min Paek of Kyungpook Nationwide College, are addressing these challenges by engineering supplies on the nanoscale. Their work, printed within the Chemical Engineering Journal on January 15, 2025, focuses on a novel hybrid materials designed to maximise the synergistic results of its parts.

This modern composite is a hierarchical heterostructure that mixes decreased graphene oxide (rGO) with nickel-iron layered double hydroxides (NiFe-LDH). This distinctive composite leverages the properties of its parts: rGO supplies a conductive community for electron transport, and the nickel-iron-oxide parts allow quick cost storage by means of a pseudocapacitive mechanism. The important thing to this innovative design is the abundance of grain boundaries, which facilitate environment friendly cost storage.

To attain the ultimate composite, the researchers employed a layer-by-layer self-assembly method utilizing polystyrene (PS) bead templates. First, the PS beads had been coated with GO and NiFe-LDH precursors. The templates had been then eliminated, forsaking a hole sphere structure.

Following this, a managed thermal therapy induced a part transformation in NiFe-LDH, resulting in the formation of nanocrystalline nickel-iron oxide (NiFe₂O₄) and amorphous nickel oxide (a-NiO), whereas concurrently lowering GO to rGO. This synthesis resulted in a well-integrated hybrid composite (rGO/NiFe₂O₄/a-NiO), with enhanced conductivity making it an environment friendly anode materials for lithium-ion batteries. This hole construction prevents direct contact between the a-NiO/NiFe₂O₄ nanoparticles and the electrolyte, enhancing stability.

Superior characterization strategies, corresponding to X-ray diffraction and transmission electron microscopyhad been then used to substantiate the composite’s formation. Electrochemical checks revealed the fabric’s distinctive efficiency as a lithium-ion battery anode.

The anode demonstrated a excessive particular capability of 1687.6 mA h g−1 at a current density of 100 mA g−1 after 580 cycles, surpassing typical supplies and highlighting its wonderful biking stability. Moreover, the fabric exhibited good charge efficiency, sustaining excessive capability even at considerably elevated cost/discharge charges.

Professor Seung-Min Paek emphasised the collaborative nature of the analysis: “This breakthrough was made possible through close cooperation between experts in diverse materials. By combining our strengths, we were able to design and optimize this hybrid system more effectively.”

Professor Jae-Min Oh added, “We anticipate that, in the near future, energy storage materials will move beyond simply improving individual components. Instead, they will involve multiple interacting materials that create synergy, resulting in more efficient and reliable energy storage devices. This research offers a pathway to smaller, lighter, and more efficient energy storage for next-generation electronic devices.”

This growth targets considerably improved batteries (longer life, sooner cost, lighter) inside 5–10 years, benefiting each gadget customers and sustainable power initiatives.

Extra info:
Minseop Lee et al, Section change-induced heterointerface engineering of hole sphere structured graphene oxide/layered double hydroxide composites for superior pseudocapacitive power storage in lithium-ion batteries, Chemical Engineering Journal (2025). DOI: 10.1016/J.Cece.2025.159671

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Dongguk College

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Hybrid anode materials advances lithium-ion battery expertise (2025, April 11)
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